Stoichiometry The stoichiometry for oxidation of p-Aminobenzhydrazide / p-Chlorobenzhydrazide by Fe(III) in the presence of PPDTS have been studied. A known excess of Fe(III) was added to a solution containing known amounts of p-Aminobenzhydrazide / p-Chlorobenzhydrazide and PPDTS. The reaction was allowed to go to completion, which is indicated by the constancy of absorbance of the reaction mixture. The amount of Fe(II) formed was computed from the absorbance at 563 nm for Fe(PPDTS)37-. The amount of Fe(II) formed is equal to the amount of Fe(III) reacted. From these values the ratio of the amount of Fe(III) and PABAH/PCBAH reacted has been calculated and the results are tabulated in Table 1. The results suggest that the stoichiometric ratio, [Fe(III)] : [PABAH] / [PCBAH] is 4 : 1. The overall reaction in the presence of PPDTS may be represented as where X = NH2 or Cl …show more content…
The pseudo-first order rate constants increase with increases in [PDTS]. Plots of 1 / kobs versus 1 / [PPDTS]2 are linear with positive slopes and positive intercepts (Figure 2) confirming the formation of 1:2 complex between Fe(III) and PPDTS. Effect of hydrogen ion It has been observed that these reactions are decelerated by hydrogen ion. Kinetic runs were performed at different [H+], keeping the concentrations of Fe(III), PPDTS and PABAH / PCBAH constant and the pseudo-first order rate constants were evaluated (Figure 3). Effect of ionic strength These reactions were also carried at different µ (0.050 to 0.30 i.e., at 0.050, 0.10, 0.150, 0.20, 0.250 and 0.30), keeping the concentrations of Fe(IIII), [PABAH] / [PCBAH], PPDTS and H+ constant. The data (Table 3.) show that ionic strength has little effect on these reactions. Determination of protonation constant of PABAH and
An error that could have been present during the lab includes not letting the zinc react completely with the chloride ions by removing the penny too early from the solution. For instance, the percent error of this lab was 45.6%, which was determined by the subtraction of the theoretical percent of Cu 2.5% and the experimental percent of Cu 3.64% and dividing by the theoretical percent of Cu 2.5%. This experiment showed how reactants react with one another in a solution to drive a chemical reaction and the products that result from the
The reason is that the iron has higher reduction potential, i.e. the ability to gain electrons, comparing to the zinc, but lower in comparison to the copper. 3. The goal of the 5th
In order to begin this experiment, first one must find the balanced chemical equation for the reaction which occurs between the aluminum and copper (II) chloride. This balanced equation being 2Al(s)+3CuCl2 (aq)3Cu(s)+2AlCl3 (aq). After finding this equation, one must use the process of stoichiometry in order to find how many grams of aluminum are needed in order to produce 0.15 grams of copper. In this experiment, the purpose was to produce between 0.1 and 0.2 grams of copper, so one should attempt to produce 0.15 grams of copper seeing as it is the average of those two numbers. The first step in the stoichiometric process which one has to complete is finding how many grams of copper are in one mole of copper.
Metal cations can be identified based on the colors they emitted off when heated in a flame.1 When atoms of the ions that were tested are excited, their electrons move up to higher levels of energy.2 When the electrons relax and return to the original states, they emit photons of specific energy creating wavelengths of light that produces colors.3 The test wire and Bunsen Burner were used to excite the solution in the crucible. The standard metal cations that were tested and their outcomes are as shown in Table 1.
After a while, a brownish color substance started to form on the three iron nails. We predicted that the brown substance on the nails is copper because the reaction of copper(II) chloride with iron is a single displacement reaction, so copper would be produced. 0.48 grams of iron was used in the reaction because 2.73 grams subtracted by 2.25 grams is 0.48 grams. The 0.48 grams of iron had to be used in the reaction with copper(II) chloride in order to produce copper, according to the reaction equation: CuCl2+FeFeCl2+Cu. 0.52 grams of copper was produced after pouring out the copper(II) chloride solution and the three iron
In the lab, the theoretical yield of CO2 was calculated by using the mass of the Alka-Seltzer (in Part A) and the mass of the anti-acid (Part B) were multiplied by the mole ratios that were involved in the reaction equation for each reaction and they were also divided by the molar mass of each substance. From the balanced chemical equations that were included in the calculation portion, the limiting reactant in part A was determined to be citric acid. The limiting reactant in part B was determined to be HCl because in the reaction, the HCl would ran out before the calcium carbonate. The stoichiometry would not have been different when converting between the different states of matter because the state is a measure of kinetic energy, and not
Introduction/Purpose: This report discusses an experiment done with copper metal. Several reactions were ran with it, which produced different copper compounds to in the end finally recover the original amount of copper. This experiment is important because it proved the Law of Conservation of Mass.
Example Problem Stoichiometry 4NH3(g) + 6NO(g)→5N2(g) + 6H2O(g) How many moles of each reactant were there if 13.7 moles of N2(g) is produced? ×4 moles NH3(g) = 10.96 moles NH3(g)
Scientists found that the stoichiometry of compounds changed periodically. If one ordered the elements by their atomic mass, you could group them by their chemical properties row after row. This grouping of elements by the compounds that they make became the periodic table. An example of a periodic chemical property is the reaction of metals with halogens (group VII elements) to make metal halides.
Pure ASA crystals are isolated from the solution with a Hirsch Funnel that was used with a filter. The melting point of the pure ASA crystals were calculated in order to calculate of absorbance. Iron (III) salicylate dianion must contain the acidified solution Fe3+ in order to measure the absorbance values. The level of the impurity can
Next, we turned our attention to the effect of oxidants. When various oxidants such as TBHP, K2S2O8, and DDQ were scrutinized (Table 1, entry 13-15), and TBHP (1 equiv) had the beneficial effect to give the best yield (Table 1, 75%; entry 13). However, the yield lowered when the amount of TBHP was decreased. The reaction did not proceed at all in the presence of other nano-particles, such as ZrO2, Fe3O4, NiO and in some copper salts CuBr2, CuCl2, (Table 1, entries
Stoichiometry is a method used in chemistry that involves using relationships between reactants and products in a chemical reaction, to determine a desired quantitative data. The purpose of the lab was to devise a method to determine the percent composition of NaHCO3 in an unknown mixture of compounds NaHCO3 and Na2CO. Heating the mixture of these two compounds will cause a decomposition reaction. Solid NaHCO3 chemically decomposes into gaseous carbon dioxide and water, via the following reaction: 2NaHCO3(s) Na2CO3(s) + H2O(g) + CO2(g). The decomposition reaction was performed in a crucible and heated with a Bunsen burner.
The labs, activities, and quizzes we have accomplished in class have taught me how electrons affect the shape of a molecule, how to predict the products of chemical reactions, and how balanced equations are used in stoichiometric calculations. The molecular geometry pogil, types of chemical reactions pogil, and the stoichiometric quiz 1 helped me understand the questions above. The electrons affect the shape of a molecule because how many electrons there are. There are many different shapes of molecular geometry.
Ideally, every mole of each reagent would be used up, and theoretical yield, we are assuming that every last mole of the reactants would
The hydrolysis formed salicylic concentration which was mixed with iron(III) solution to form a purple complex. This was then use to study under the UV/Visible absorption spectroscopy which gave absorbance values recorded at 525nm to determine the concentration of salicylic acid using the Beer Lambert’s Law and later corrected to find the actual concentrations. The concentrations of aspirin at various intervals was found from salicylic concentrations. Upon plotting a graph of ln(aspirin) vs time, it produced a linear equation from which the gradient gave the rate constant of 0.0083min-1 and the overall shape of the graph concluding this reaction to be pseudo first order with respect to the concentration of aspirin with the deviations and improvements as